[60]fullerene-stoppered porphyrinorotaxanes: pronounced elongation of charge-separated-state lifetimes.
نویسندگان
چکیده
A series of Sauvage-type porphyrinorotaxanes containing [60]fullerene stoppers have been synthesized by a convergent route. Photoinduced energy transfer and electron-transfer reactions in these rotaxanes yield long-distance charge-separated radical-pair states, whose lifetimes in solution at ambient temperatures are as high as 32 mus, depending on the distance between the fullerene and zinc porphyrin chromophores.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 126 30 شماره
صفحات -
تاریخ انتشار 2004